| 000 | 05925nam a2200709 a 4500 | ||
|---|---|---|---|
| 001 | EBC954643 | ||
| 003 | MiAaPQ | ||
| 005 | 20180702100642.0 | ||
| 007 | cr cn |||m|||a | ||
| 008 | 120913s2012 nyua foab 001 0 eng d | ||
| 020 | _a9781606503522 (electronic bk.) | ||
| 020 | _a1606503529 (electronic bk.) | ||
| 020 | _z9781606503508 (print) | ||
| 020 | _z1606503502 (print) | ||
| 024 | 7 |
_a10.5643/9781606503522 _2doi |
|
| 035 | _a(OCoLC)809804677 | ||
| 035 | _a(CaBNvSL)swl00401257 | ||
| 035 | _a(MiAaPQ)EBC954643 | ||
| 035 | _a(Au-PeEL)EBL954643 | ||
| 035 | _a(CaPaEBR)ebr10588196 | ||
| 035 | _a(CaONFJC)MIL420849 | ||
| 035 | _a(OCoLC)830170650 | ||
| 040 |
_aMiAaPQ _cMiAaPQ _dMiAaPQ |
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| 050 | 4 |
_aQD96.N8 _bA668 2012 |
|
| 082 | 0 | 4 |
_a543.0877 _223 |
| 100 | 1 | _aApperley, David C. | |
| 245 | 1 | 0 |
_aSolid-state NMR _h[electronic resource] : _bbasic principles & practice / _cDavid C. Apperley, Robin K. Harris & Paul Hodgkinson. |
| 260 |
_a[New York, N.Y.] (222 East 46th Street, New York, NY 10017) : _bMomentum Press, _c2012. |
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| 300 |
_a1 electronic text (xiv, 276 p.) : _bill., digital file. |
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| 504 | _aIncludes bibliographical references and index. | ||
| 505 | 0 | _aPreface -- About the authors -- | |
| 505 | 8 | _a1. Introduction -- 1.1 The utility of NMR -- 1.2 A preview of solid-state NMR spectra -- 1.3 The solid state -- 1.4 Polymorphism, solvates, co-crystals & host:guest systems -- 1.5 NMR of solids & the periodic table -- | |
| 505 | 8 | _a2. Basic NMR concepts for solids -- 2.1 Nuclear spin magnetization -- 2.2 Tensors -- 2.3 Shielding -- 2.4 Indirect coupling -- 2.5 Dipolar coupling -- 2.6 Quadrupolar coupling -- 2.7 Magic-angle spinning -- 2.8 Relaxation -- | |
| 505 | 8 | _a3. Spin-1/2 nuclei: a practical guide -- 3.1 Introduction -- 3.2 The vector model & the rotating frame of reference -- 3.3 The components of an NMR experiment -- 3.4 Cross polarization -- 3.5 High-resolution spectra from 1H (& 19F) -- | |
| 505 | 8 | _a4. Quantum mechanics of solid-state NMR -- 4.1 Introduction -- 4.2 The Hamiltonians of NMR -- 4.3 The density matrix -- 4.4 Density operator treatments of simple NMR experiments -- 4.5 The density matrix for coupled spins -- 4.6 Euler angles & spherical tensors -- 4.7 Additional analytical tools -- | |
| 505 | 8 | _a5. Going further with spin-1/2 solid-state NMR -- 5.1 Introduction -- 5.2 Linewidths in solid-state NMR -- 5.3 Exploiting indirect (J) couplings in solids -- 5.4 Spectral correlation experiments -- 5.5 Homonuclear decoupling -- 5.6 Using correlation experiments for spectral assignment -- 5.7 Further applications -- | |
| 505 | 8 | _a6. Quadrupolar nuclei -- 6.1 Introduction -- 6.2 Characteristics of first-order quadrupolar spectra -- 6.3 First-order energy levels & spectra -- 6.4 Second-order zero-asymmetry cases -- 6.5 Spectra for cases with non-zero asymmetry: central transition -- 6.6 Recording one-dimensional spectra of quadrupolar nuclei -- 6.7 Manipulating the quadrupolar effect -- 6.8 Spectra for integral spins -- | |
| 505 | 8 | _a7. Relaxation, exchange & quantitation -- 7.1 Introduction -- 7.2 Relaxation -- 7.3 Exchange -- 7.4 Quantitative NMR -- 7.5 Paramagnetic systems -- | |
| 505 | 8 | _a8. Analysis & interpretation -- 8.1 Introduction -- 8.2 Quantitative measurement of anisotropies -- 8.3 Measurement of dipolar couplings -- 8.4 Quantifying indirect (J) couplings -- 8.5 Tensor interplay -- 8.6 Effects of quadrupolar nuclei on spin-1/2 spectra -- 8.7 Quantifying relationships between tensors -- 8.8 NMR crystallography -- | |
| 505 | 8 | _aAppendices -- A. The spin properties of spin-1/2 nuclides -- B. The spin properties of quadrupolar nuclides -- C. Liouville space, relaxation & exchange -- C.1 Introduction to Liouville space -- C.2 Application to relaxation -- C.3 Application to chemical exchange -- D. Introduction to solid-state NMR simulation -- D.1 Specifying the spin system -- D.2 Specifying the powder sampling -- D.3 Specifying the pulse sequence -- D.4 Efficiency of calculation -- Index. | |
| 506 | _aRestricted to libraries which purchase an unrestricted PDF download via an IP. | ||
| 520 | 3 | _aNuclear magnetic resonance (NMR) has proved to be a uniquely powerful and versatile spectroscopy, and no modern university chemistry department or industrial chemistry laboratory is complete without a suite of NMR spectrometers. The phenomenon of nuclear spin may seem an odd basis for an analytical tool, but it is the relative isolation of the nuclear spin from its surroundings that makes it an ideal noninterfering probe of the electronic environment. Different sites are clearly identified by their chemical shifts, while J couplings in 1H spectra provide connectivity information. The combination of these two complementary interactions, plus the formidable array of different NMR experiments developed since the arrival of Fourier transform NMR in 1966, has revolutionized the practice of chemistry. | |
| 530 | _aAlso available in print. | ||
| 533 | _aElectronic reproduction. Ann Arbor, MI : ProQuest, 2015. Available via World Wide Web. Access may be limited to ProQuest affiliated libraries. | ||
| 538 | _aMode of access: World Wide Web. | ||
| 538 | _aSystem requirements: Adobe Acrobat reader. | ||
| 588 | _aTitle from PDF t.p. (viewed on September 13, 2012). | ||
| 650 | 0 | _aNuclear magnetic resonance spectroscopy. | |
| 653 | _aSolid-state NMR | ||
| 653 | _aMagic-angle spinning | ||
| 653 | _aSolid-state structure | ||
| 653 | _aNMR crystallography | ||
| 653 | _aCross polarization | ||
| 653 | _aQuadrupolar nuclei | ||
| 655 | 4 | _aElectronic books. | |
| 700 | 1 |
_aHarris, Robin K. _q(Robin Kingsley) |
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| 700 | 1 | _aHodgkinson, Paul. | |
| 776 | 0 | 8 |
_iPrint version: _z1606503502 _z9781606503508 |
| 856 | 4 | 0 |
_uhttps://ebookcentral.proquest.com/lib/kliuc-ebooks/detail.action?docID=954643 _zClick to View |
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